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Here are the results of the first 5 matches:
| 1 | China (CHN) | Rtg | – | 67 | Luxembourg (LUX) | Rtg | 4 : 0 |
| GM | | 2583 | – | WIM | | 2159 | 1 – 0 |
| GM | | 2522 | – | WFM | | 1953 | 1 – 0 |
| WGM | | 2475 | – | | | 1898 | 1 – 0 |
| IM | | 2417 | – | | | 1844 | 1 – 0 |
| 68 | Portugal (POR) | Rtg | – | 2 | Ukraine (UKR) | Rtg | 0 : 4 |
| WFM | | 2125 | – | GM | | 2539 | 0 – 1 |
| WFM | | 2078 | – | GM | | 2475 | 0 – 1 |
| | 1789 | – | GM | | 2457 | 0 – 1 |
| | Silva, Ana Ines Teixeira Da |
| 1855 | – | IM | | 2416 | 0 – 1 |
| 3 | Russia (RUS) | Rtg | – | 69 | Scotland (SCO) | Rtg | 4 : 0 |
| GM | | 2538 | – | GM | | 2381 | 1 – 0 |
| WGM | | 2475 | – | | | 1894 | 1 – 0 |
| WGM | | 2484 | – | WFM | | 1894 | 1 – 0 |
| WGM | | 2452 | – | | | 1679 | 1 – 0 |
| 83 | Nicaragua (NCA) | Rtg | – | 16 | Azerbaijan 1 (AZE) | Rtg | 0 : 4 |
| WFM | | 1943 | – | WGM | | 2295 | 0 – 1 |
| WIM | | Granados Diaz, Maria Esther |
| 1831 | – | WGM | | 2304 | 0 – 1 |
| | 1834 | – | WFM | | 2339 | 0 – 1 |
| | 1732 | – | WGM | | 2302 | 0 – 1 |
| 70 | ICCD (ICCD) | Rtg | – | 4 | Georgia (GEO) | Rtg | 0 : 4 |
| WIM | | 2200 | – | IM | | 2486 | 0 – 1 |
| | 1910 | – | GM | | 2463 | 0 – 1 |
| | 1922 | – | IM | | 2474 | 0 – 1 |
| | 1807 | – | IM | | 2419 | 0 – 1 |
Some games of the round
Pairings of first 5 matches of the 2nd round
| 1 | 42 | | MNE | Montenegro | 4 | 2 | | : | | 2 | 4 | China | CHN | | 1 |
| 2 | 2 | | UKR | Ukraine | 4 | 2 | | : | | 2 | 4 | Moldova | MDA | | 44 |
| 3 | 45 | | ECU | Ecuador | 4 | 2 | | : | | 2 | 4 | Russia | RUS | | 3 |
| 4 | 16 | | AZE | Azerbaijan 1 | 4 | 2 | | : | | 2 | 4 | Mexico | MEX | | 57 |
| 5 | 4 | | GEO | Georgia | 4 | 2 | | : | | 2 | 4 | Philippines | PHI | | 46 |
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